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梁永民

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梁永民

博士、教授

电话:+86-931-8912589

传真:+86-931-8912582

邮箱: liangym@lzu.edu.cn

教育背景、工作经历

1992-至今            兰州大学化学化工学院、功能有机分子化学国家重点实验室

2001-2002           台湾清华大学,访问学者

1996-1998           兰州大学 (导师: 马永祥),理学博士

1989-1992           兰州大学 (导师: 马永祥),理学硕士

1985-1989           陕西师范大学,理学学士

研究兴趣

均相催化,药物分子合成以及有机材料化学

代表成果

1. Synthesis of C4-Aminated Indoles via a Catellani and Retro-Diels− Alder Strategy. Bo-Sheng Zhang, Yuke Li, Zhe Zhang, Yang An, Yu-Hua Wen, Xue-Ya Gou, Si-Qi Quan, Xin-Gang Wang, and Yong-Min Liang*. J. Am. Chem. Soc., 2019, 141, 9731−9738.

2. Three-Component Ruthenium-Catalyzed Direct Meta-Selective C−H Activation of Arenes: A New Approach to the Alkylarylation of Alkenes. Xin-Gang Wang, Yuke Li, Hong-Chao Liu, Bo-Sheng Zhang, Xue-Ya Gou, Qiang Wang, Jun-Wei Ma, and Yong-Min Liang*. J. Am. Chem. Soc., 2019, 141, 13914−13922.

3. Ligand-controlled regiodivergent p-allyl palladium catalysis enables a switch between [3+2] and [3+3] cycloadditions. Yu Xia, Qiao-Fei Bao, Yuke Li, Li-Jing Wang,  Bo-Sheng Zhang, Hong-Chao Liu and Yong-Min Liang*. Chem. Commun., 2019, 55, 4675−4678.

4. Ruthenium-catalyzed ortho-selective CAr–H amination of heteroaryl arenes with di-tert-butyldiaziridinone. Xue-Ya Gou, Yuke Li, Xin-Gang Wang, Hong-Chao Liu, Bo-Sheng Zhang, Jia-Hui Zhao, Zhao-Zhao Zhou and Yong-Min Liang*. Chem. Commun., 2019, 55, 5487−5490.

5. Metal-Free Promoted CF2/CF3-Difunctionalization of Unactivated Alkenes. Ming Li, Xin-Yu Zhu, Yi-Feng Qiu, Ya-Ping Han, Yu Xia, Cui-Tian Wang, Xue-Song Li, Wan-Xu Wei, and Yong-Min Liang*. Adv. Synth. Catal., 2019, 361, 2945−2950.

6. Transition-Metal-Free Alkylation/Arylation of Benzoxazole via Tf2O-Activated-Amide. Zhi-Jie Niu, Lian-Hua Li, Xue-Yuan Liu* and Yong-Min Liang*. Adv. Synth. Catal., 2019, 361, 5217−5222.

7. Visible-light-mediated hydrodehalogenation and Br/D exchange of inactivated aryl and alkyl halides with a palladium complex. Zhao-Zhao Zhou, Jia-Hui Zhao, Xue-Ya Gou, Xi-Meng Chen* and Yong-Min Liang*. Org. Chem. Front., 2019, 6, 1649–1654.  

8. Palladium-Catalyzed Intramolecular Self-Alkylation of Polyfluoroarene via Heck and Decarboxylation Process. Wan-Xu Wei, Si Chen, Yu Xia, Ming Li, Xue-Song Li, Ya-Ping Han, Cui-Tian Wang, and Yong-Min Liang*. ChemCatChem., 2019, 11, 5754−5757. 

Synthesizing Functional Biomacromolecular Wet Adhesives with Typical Gel−Sol Transition and Shear-Thinning Features. Luyao Gao, Shuanhong Ma, Jiajun Luo, Guangjie Bao,Yang Wu, Feng Zhou, and Yong-Min Liang*. ACS Biomater. Sci. Eng., 2019, 5, 4293−4301.  

9. Carboxylate Ligand-Exchanged Amination/C(sp3)−H Arylation Reaction via Pd/ Norbornene Cooperative Catalysis. Bo-Sheng Zhang, Yuke Li, Yang An, Zhe Zhang, Ce Liu, Xin-Gang Wang, and Yong-Min Liang*. ACS Catal., 2018, 8, 11827.

10. Three-component difluoroalkylation and trifluoromethylthiolation/ trifluoro- methylselenolation of p-bonds. Bo-Sheng Zhang, Lu-Yao Gao, Zhe Zhang, Yu-Hua Wen and Yong-Min Liang*. Chem. Commun., 2018, 54, 1185.

11. Synthesis of polyfluoroarene-substituted benzofuran derivatives via cooperative Pd/Cu catalysis. Yi Shen, Xin-Xing Wu, Si Chen, Yu Xia and Yong-Min Liang*. Chem. Commun., 2018, 54, 2256.

12. Synthesis of indolines via a palladium/norbornene-catalyzed reaction of aziridines with aryl iodides. Ce Liu, Yujie Liang, Nian Zheng, Bo-Sheng Zhang, Yuan Feng, Siwei Bi*and Yong-Min Liang*. Chem. Commun., 2018, 54, 3407.

13. Base promoted direct difunctionalization/cascade cyclization of 1,6-enynes. Ming Li, Cui-Tian Wang, Yi-Feng Qiu,  Xin-Yu Zhu, Ya-Ping Han, Yu Xia,Xue-Song Li and Yong-Min Liang*. Chem. Commun., 2018, 54, 5334.

14. Ruthenium(II)-catalyzed selective C–H difluoroalkylation of aniline derivatives with pyrimidyl auxiliaries. Xin-Gang Wang, Yuke Li, Lu-Lu Zhang, Bo-Sheng Zhang, Qiang Wang, Jun-Wei Ma and Yong-Min Liang*. Chem. Commun., 2018, 54, 9541.

15. Transition-metal-free multinitrogenation of amides by C–C bond cleavage: a new approach to tetrazoles. Lian-Hua Li, Zhi-Jie Niu, Ying-Xiu Li and Yong-Min Liang*. Chem. Commun., 2018, 54, 11148.

16. Brønsted Acid-Mediated Formal [3+3] Annulation Between Propargylic Alcohols and 1,3-Diketones. Ya-Ping Han, Xue-Song Li, Xin-Yu Zhu, Zhou Sun, Ming Li, Yu-Zhao Wang, Yong-Min Liang*. Adv. Synth. Catal., 2018, 360, 870.

17. Lewis Acid-Catalyzed Formal [3+3] Annulation of Propargylic Alcohols with 4-Hydroxy-2H-chromen-2-ones. Ya-Ping Han, Xue-Song Li, Ming Li, Xin-Yu Zhu, and Yong-Min Liang*. Adv. Synth. Catal., 2018, 360, 2796.

18. Copper-Catalyzed Radical Sulfonylation of N-Propargylindoles with Concomitant 1,2-Aryl Migration. Xin-Yu Zhu, Ya-Ping Han, Ming Li, Xue-Song Li, and Yong-Min Liang*. Adv. Synth. Catal., 2018, 360, 3460.

19. Lewis Acid-Catalyzed Annulation of Propargylic Alcohols with (Z)-2-Styryl-1H-Indoles. Xue-Song Li, Ya-Ping Han, Xin-Yu Zhu, Yu Xia, Wan-Xu Wei, Ming Li, and Yong-Min Liang*. Adv. Synth. Catal., 2018, 360, 4441.

20. Palladium-Catalyzed Cascade Difluoroalkylation/Cyclization of N‑Propargylamides: Synthesis of Oxazoles and Oxazolines. Jun-Wei Ma, Qiang Wang, Xin-Gang Wang, and Yong-Min Liang*. J. Org. Chem., 2018, 83, 13296.

21. Synthesis of Difluoroalkyl Unsaturated β‑Amino Acid Derivatives. Qiang Wang, Jia-Ni Jin, Xi Chen, Xin-Gang Wang, Bo-Sheng Zhang, Jun-Wei Ma, and Yong-Min Liang*. J. Org. Chem., 2018, 83, 14626.

22. New Friedel–Crafts strategy for preparing 3-acylindoles. Lian-Hua Li, Zhi-Jie Niu and Yong-Min Liang*. Org. Biomol. Chem., 2018, 16, 7792.

23. Difunctionalization of Alkynes: Synthesis of Novel Fluoropolymer Materials. Qiang Wang, Xiwen Yu, Jiani Jin, Yang Wu, and Yongmin Liang*. Chin. J. Chem., 2018, 36, 223.

24. Regioselective Synthsis of Difluoroalkyl/Perfluoroalkyl Enones via Pd-Catalyzed Four-component Carbonylative Coupling Reactions. Qiang Wang, Lan Zheng, Yu-Tao He, Yong-Min Liang* Chem. Commun. 2017, 53, 2814-2817.

25. Synthesis of Functionalized Quinolines through a Reaction of Amides and Alkynes Promoted by Triflic Anhydride/Pyridine. Lian-Hua Li, Zhi-Jie Niu, and Yong-Min Liang* Chem. Eur. J. 2017, 23, 15300-15304.

26. Lewis Acid-Catalyzed [4+2] Annulation between Propargylic Alcohols with Benzo[d]isoxazoles. Ya-Ping Han, Xue-Song Li, Zhou Sun, Xin-Yu Zhu, Ming Li, Xian-Rong Song, and Yong-Min Liang* Adv. Synth. Catal. 2017, 359, 2735-2740.

27. Palladium-Catalyzed Isocyanide Insertion with Allylic Esters: Synthesis of N-(But-2-enoyl)-N-(tert-butyl) benzamide Derivatives via Intramolecular Acyl Transfer Termination. Si Chen, Wan-Xu Wei, Jia Wang, Yu Xia, Yi Shen, Xin-Xing Wu, Huanwang Jing,* and Yong-Min Liang* Adv. Synth. Catal. 2017, 359, 3538-3544.

28. Lewis Acid Catalyzed [4+3] Cycloaddition of Propargylic Alcohols with Azides. Ya-Ping Han, Xian-Rong Song, Yi-Feng Qiu, Heng-Rui Zhang, Lian-Hua Li, Dong-Po Jin, Xiao-Qing Sun, Xue-Yuan Liu, and Yong-Min Liang*. Org. Lett., 2016, 18, 940.

29. Palladium-Catalyzed Regioselective Difluoroalkylation and Carbonylation of Alkynes. Qiang Wang, Yu-Tao He, Jia-Hui Zhao, Yi-Feng Qiu, Lan Zheng, Jing-Yuan Hu, Yu-Chen Yang, Xue-Yuan Liu, and Yong-Min Liang*. Org. Lett., 2016, 18, 2664.

30. Lewis Acid Catalyzed Cyclization of Propargylic Alcohols with 2‑Vinylphenol. Ya-Ping Han, Xian-Rong Song, Yi-Feng Qiu, Xue-Song Li, Heng-Rui Zhang, Xin-Yu Zhu, Xue-Yuan Liu, and Yong-Min Liang*. Org. Lett., 2016, 18, 3866.

31. Synthesis of β‑Difluoroalkylated Acrylonitriles in the Presence of Copper Powder. Yu-Tao He, Lian-Hua Li, Qiang Wang, Wangsuo Wu, and Yong-Min Liang*. Org. Lett., 2016, 18, 5158.

32. Copper-catalyzed difluoromethylation of propargylamide-substituted indoles: synthesis of mono- and bis-difluoromethylated indoloazepinone derivatives. Hui-Liang Hua, Bo-Sheng Zhang, Yu-Tao He, Yi-Feng Qiu, Jing-Yuan Hu, Yu-Chen Yang and Yong-Min Liang*. Chem. Commun., 2016, 52, 10396.

33. AgSCF3‑Mediated Trifluoromethylthiolation/Radical Cascade Cyclization of 1,6-Enynes. Yi-Feng Qiu, Xin-Yu Zhu, Ying-Xiu Li, Yu-Tao He, Fang Yang, Jia Wang Hui-Liang Hua, Lan Zheng, Li-Chen Wang, Xue-Yuan Liu, and Yong-Min Liang*. Org. Lett., 2015, 17, 3694-3697.

34. Metal-free nitro-carbocyclization of 1,6-enynes with tBuONO and TEMPO. Xin-Hua Hao, Pin Gao, Xian-Rong Song, Yi-Feng Qiu, Dong-Po Jin, Xue-Yuan Liu and Yong-Min Liang*. Chem. Commun., 2015, 51, 6839-6842.

35. Palladium-Catalyzed Acylation/Alkenylation of Aryl Iodide: A Domino Approach Based on the Catellani–Lautens Reaction. Ping-Xin Zhou, Yu-Ying Ye, Ce Liu, Lian-Biao Zhao, Jian-Ye Hou, Dao-Qian Chen, Qian Tang, An-Qi Wang, Jie-Yu Zhang, Qi-Xing Huang, Peng-Fei Xu*, and Yong-Min Liang*. ACS Catal., 2015, 5, 4927-4931.

36. Copper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/ Carbonyl Formation with Homopropargylic Alcohols. Pin Gao, Shen, Yong-Wen Shen, Ran Fang, Xin-Hua Hao, Zi-Hang Qiu, Fan Yang, Xiao-Biao Yan, Qiang Wang, Xiang-Jun Gong, Xue-Yuan Liu,* Yong-Min Liang,* Angew. Chem. Int. Ed. 2014, 53, 7629 -7633.

37. Palladium-Catalyzed C-H Activation and Intermolecular Annulation with Allenes. Xiao-Feng Xia, Yu-Qi Wang, Lu-Lu Zhang, Xian-Rong Song, Xue-Yuan Liu, Yong-Min Liang*. Chem. Eur. J. 2014, 20, 5087 -5091.

38. Silver-catalyzed carbon–phosphorus functionalization of N-(p-methoxyaryl)propiolamides coupled with dearomatization: access to phosphorylated aza-decenones. Li-Jing Wang, An-Qi Wang, Yu Xia, Xin-Xing Wu, Xue-Yuan Liu and Yong-Min Liang*. Chem. Commun., 2014, 50, 13998-13401.

39. Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes. Yu-Tao He, Lian-Hua Li, Yan-Fang Yang, Zhao-Zhao Zhou, Hui-Liang Hua, Xue-Yuan Liu, Yong-Min Liang*. Org. Lett. 2014, 16, 270-273.

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