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韩 丙

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韩丙

博士、教授

电话:+86-931-8912500

邮箱: hanb@lzu.edu.cn

·教育背景、工作经历

2008-至今            兰州大学化学化工学院、功能有机分子化学国家重点实验室,讲师、副教授、教授

2006-2007           休斯顿大学 (导师: Jay K. Kochi),博士后

2001-2006           兰州大学 (导师: 刘中立),理学博士

1996-2000           西北师范大学,理学学士

·研究兴趣

自由基化学, 物理有机化学,绿色反应方法学

·代表成果

1. 4-HO-TEMPO-Catalyzed Redox Annulation of Cyclopropanols with Oxime Acetates toward Pyridine Derivatives, Jun-Long Zhan, Meng-Wei Wu, Dian Wei, Bang-Yi Wei, Yu Jiang, Wei Yu, and Bing Han*, ACS Catal. 2019, 9, 4179−4188.

2. Silver-Catalyzed Site-Selective Ring-Opening and C–C Bond Functionalization of Cyclic Amines: Access to Distal Amino-Alkyl Side-Chain-Containing Quinones, Rui-Hua Liu, Yi-Heng He, Wei Yu, Bo Zhou, and Bing Han*, Org. Lett. 2019, 21, 4590−4594.

3. Theoretical study on the mechanism and chemoselectivity in gold(I)-catalyzed cycloisomerization of β,β-disubstituted ortho-(alkynyl)styrenes, Lin Zhou,   Li Yang,   Yanwen Zhang,   Alexander M. Kirillov,  Ran Fang,* and Bing Han*, Org. Chem. Front. 2019, 6, 2701-2712.

4. Decarboxylative Borylation of mCPBA-Activated Aliphatic Acids,Wei, Dian; Liu, Tu-Ming; Zhou, Bo; Han, Bing, Org. Lett. 2019, 10.1021/acs.orglett.9b04218.

5. Deconstructive Oxygenation of Unstrained Cycloalkanamines, Angew. Chem. Int. Ed. 2019, 10.1002/anie.201914623.

6. Cu-Catalyzed Radical Cascade Annulations of Alkyne-Tethered N-Alkoxyamides with Air: Facile Access to Isoxazolidine/1,2-Oxazinane-Fused Isoquinolin-1(2H)‑ones, Fei Chen, Sheng-Qiang Lai, Fei-Fei Zhu, Qiang Meng, Yu Jiang, Wei Yu, and Bing Han*, ACS Catal. 2018, 8, 8925−8931.

7. Cu-Catalyzed Aminoacyloxylation of Unactivated Alkenes of Unsaturated Hydrazones with Manifold Carboxylic Acids toward Ester-Functionalized Pyrazolines, Rui-Hua Liu, Zi-Qing Wang, Bang-Yi Wei, Jian-Wu Zhang, Bo Zhou, and Bing Han*, Org. Lett. 2018, 20, 4183−4186.

8. Cu-Catalyzed Oxyalkynylation and Aminoalkynylation of Unactivated Alkenes: Synthesis of Alkynyl-Featured Isoxazolines and Cyclic Nitrones, Wen-Jun Han, Yuan-Rui Wang, Jian-Wu Zhang, Fei Chen, Bo Zhou, and Bing Han*, Org. Lett. 2018, 20, 2960-2963.

9. Synthesis of Halomethyl Isoxazoles/Cyclic Nitrones via Cascade Sequence: 1,2-Halogen Radical Shift as a Key Link, Hong-Lei Chen, Dian Wei, Jian-Wu Zhang, Cheng-Lin Li, Wei Yu, and Bing Han*, Org. Lett. 2018, 20, 2906-2910.

10. “Dioxygen Activation via Cu-Catalyzed Cascade Radical Reaction: An Approach to Isoxazoline/Cyclic Nitrone-Featured α-Ketols”, Peng, X.-X.;† Wei D.;† Han, W.-J.;† Chen, F.; Yu, W.; Han B.*, ACS Catal. 2017, 7, 7830−7834.

11. “Copper-Catalyzed Cascade Cyclization of 1,7-Enynes toward Trifluoromethyl- Substituted 1’H‑Spiro[azirine-2,4’-quinolin]-2’(3’H)-ones”, Meng, Q.; Chen, F.; Yu, W.* Han, B.*, Org. Lett. 2017, 19, 5186-5186.

12. “Iminoxyl Radical-Promoted Oxycyanation and Aminocyanation of Unactivated Alkenes: Synthesis of Cyano-Featured Isoxazolines and Cyclic Nitrones”, Chen, F.; Zhu, F.-F.; Zhang, M. Liu, R.-H.; Yu, W.; Han, B. Org. Lett. 2017, 19, 3255-3258.

13. “Cu-catalyzed [3+3] annulation for the synthesis of pyrimidines via β-C(sp3)−H functionalization of saturated ketones”, Zhan, J.-L.; Wu, M.-W.; Chen, F.; Han, B.*, J. Org. Chem. 2016, 81,11994–12000.

14. “Copper-Catalyzed Oxidative Oxyamination/Diamination of Internal Alkenes of Unsaturated Oximes with Simple Amines,” Liu, R.-H. Wei, D.; Han, B.*, Yu, W.*, ACS Catal. 2016, 6, 6525–6530.

15. “TBHP-Initiated Vicinal Sulfonamination of Alkynes: A Radical Annulation toward 3-Sulfonylindoles”, Chen, F.; Meng, Q.; Han, S.-Q.; Han, B.*, Org. Lett. 2016, 18, 3330–3333.

16. “TEMPO-Mediated Aza-Diels–Alder Reaction: Synthesis of Tetrahydropyridazines Using Ketohydrazones and Olefins”, Yang, X.-L.; Peng, X.-X.; Chen, F.; Han, B.* Org. Lett. 2016, 18, 2070–2073.

17. “Synthesis of Isoxazoline/Cyclic Nitrone-Featured Methylenes Using Unsaturated Ketoximes: A Dual Role of TEMPO”, Chen, F.; Yang, X.-L.; Wu, Z.-W.; Han, B.* J. Org. Chem. 2016, 81, 3042–3050.

18. “Hydrazonyl Radical-Participated Tandem Reaction: A Strategy for the Synthesis of Pyrazoline-Functionalized Oxindoles”, Duan, X.-Y.; Jia P.-P.; Zhang, M.; Han, B.* Org. Lett. 2015, 17, 6022−6025.

19. “Transition from π Radicals to σ Radicals: Substituent-Tuned Cyclization of Hydrazonyl Radicals”, Duan, X.-Y.; Zhou, N.-N.; Fang, R.; Yang, X.-L.; Yu, W.;Han, B.* Angew. Chem. Int. Ed. 2014, 53, 3158–3162.

20. “Iminoxyl Radical-Promoted Dichotomous Cyclizations: Efficient Oxyoximation and Aminooximation of Alkenes”, Peng, X.-X.; Deng, Y.-J.; Yang, X.-L.; Zhang, L.; Yu, W.; Han, B.* Org. Lett. 2014, 16, 4650−4653.

21. “Synthesis of Isoxazoline-Functionalized Phenanthridines via Iminoxyl Radical- Participated Cascade Sequence”, Yang, X.-L.; Chen, F.; Zhou, N.-N.; Yu, W.; Han, B.* Org. Lett. 2014, 16, 6476−6479.

22. “Hydrazone Radical Promoted Vicinal Difunctionalization of Alkenes and Trifunctionalization of Allyls: Synthesis of Pyrazolines and Tetrahydropyridazines”, Duan, X.-Y.; Yang, X.-L.; Fang, R.; Peng, X.-X.; Yu, W. Han B.* J. Org. Chem. 2013, 78, 10692–10704.

23. “Oxime Radical Promoted Dioxygenation, Oxyamination and Diamination of Alkenes: Synthesis of Isoxazolines and Cyclic Nitrones,”Han, B.*; Yang, X.-L.; Fang, R.; Yu, W.; Wang, C.; Duan, X.-Y.; Liu, S. Angew. Chem. Int. Ed. 2012, 51, 8816–8820.

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