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刘有成

【来源:功能有机分子化学国家重点实验室 | 发布日期: | 作者: 】     【选择字号:
刘有成,男,教授,现任中国科学技术大学化学系教授和兰州大学化学系教授。 中国科学院院士。
1920年11月出生,安徽省舒城县人。1942年毕业于中央大学。1945年经过考试获奖学金赴英国留学,1948年由利兹大学获得哲学博士学位,专业有机化学。随后赴美国西北大学从事博士后研究,1951年到芝加哥大学随卡拉施(M. S. Kharasch)教授任博士后研究员。1954年回国。1955年到兰州大学工作,历任化学系教授,系主任,系名誉主任,校学术委员会主任。1980年当选为中国科学院院士(学部委员)。1987年应国家教委聘任兰州大学应用有机化学国家重点实验室主任兼学术委员会主任。1994年起任中国科学技术大学化学系教授。是第六届全国人民代表大会代表。
发表论文250余篇。由他编著的《自由基化学》获1982年国家自然科学奖三等奖,《单电子转移反应研究》获国家教委1987年、1995年科技进步一等奖。1986年被评为全国教育系统劳动模范,获人民教师奖章。1990年被评为全国高等学校先进科技工作者。
主要从事的研究领域
(1) 自由基化学
(2) 单电子转移反应
(3) 辅酶NADH模型物反应机理
联系电话:0551-3603254
传      真:0551-3603254
E-mail:ycliu@ustc.edu.cn
代表性论文目录:
1. Mechanism of Reduction of 1,1-Diphenyl-2,2-dinitroethylene by 1-Benzyl-1,4-dihydronicotinamide,Transition State with Partial Diradical and Partial Covalent Bonding Character, You-Cheng Liu, Hong-Yi Wang, Qing-Chuan Yang and Thomas C.W. Mak, J. Chem. Soc. Perkin Trans., 2000, 2, 649-653.
2. Asymmetric reduction of 2-bromo-1-phenylethylidenemalononitrile with chiral NADH models: substituent effects on enantioselectivity, Jing Li, You-Cheng Liu, Jing-Gen Deng, Xing-Zhu Li, Xing Cui, Zhi Li, Tetrahedron-Asymmetry, 2000, 11, 2677-2682.
3. Stereoselective Reduction with NADH Model BNAH through Chiral Induction in Cyclodextrins, You-Cheng Liu, Xin-Zhu Li, Chao Yang, Qing-Xiang Guo, Bioorg. Chem., 2001, 29, 14-18.
4. Novel Photoinduced Coupling Reaction of 9-Fluorenylidenemalononitrile with 10-Methyl-9,10-dihydroacridine, Hong Jiang, You-Cheng Liu, Jing Li, Guan-Wu Wang, Yun-Dong Wu, Quan-Ming Wang, and Thomas C.W. Mak, Chem. Commun., 2002, 882-883.
5. Thermal and photoinduced reduction of some benzyl bromides by an NAD(P)H model, the effect of electron withdrawing groups on mechanism and reactivity, Hong-Yi Wang, Dan-Mei Dai, You-Cheng Liu, and Qing-Xiang Guo, Tetrahedron Lett., 2002, 43, 7527-7530.
6. Photo-induced Coupling Reactions of 9-Fluorenylidenemalononitrile and 1,1-Diphenyl-2,2-dicyanoethylene with 10-Methyl- 9,10-dihydroacridine-A Study on the Photophysics  of  the  Reaction, Hong Jiang, You-Cheng Liu, Guan-Wu Wang, Li-Zhu Wu, Zhen-He Tong, Chin. J. Chem., 2003 , 21, 1400-1402.
7. Reaction of 1,1-Di-p-methoxyphenyl-2,2-dinitroethylene and 1, 1-Di-o-methoxyphenyl-2,2- dinitroethylene with 1-Benzyl-1,4-dihydronicotinamide: Evidence for Concerted Electron- Hydrogen Atom Transfer Mechanism, Dan-Mei Dai, You-Cheng Liu, Jing Li, Pei Wang, Xu-Dong Chen, and Thomas C. W. Mak, Chin. Chem. Lett., 2004, 15(3), 353-356.
8. Mechanistic investigation on the reaction of 1,1-di-p-substituted phenyl-2,2-dinitroethylene with 1-benzyl-1,4-dihydronicotinamide in oxygen saturated acetonitrile. Clear evidence for intermediate mechanism, Hua-Jian Xu, Dan-Mei Dai, You-Cheng Liu, Jing Li, Shi-Wei Luo, Yun-Dong Wu, Tetrahedron Lett., 2005, 46, 5739-5742.
9. A novel coenzyme NADH model 1-benzyl-1,4-dihydronicotinamide-mediated reaction: a single intermediate erves two mechanisms, Xin-Qiang Fang, You-Cheng Liu, Guan-Wu Wang, Yu-Ping Ke, Res. Chem. Intermed., 2006, 32, 603-611.
10. Catalytic Hydrogenation of a, b-Epoxy Ketones to Form b-Hydroxy Ketones Mediated by an NADH Coenzyme Model, Hua-Jian Xu, You-Cheng Liu, Yao Fu, Yun-Dong Wu, Org. Lett., 2006, 8, 3449-3451.
2006年以前文章:
1. Mechanistic Studies on the Reduction of 2-Bromo-1-phenylethylidenemalononitrile by NADH Models BNAH and AcrH2, You-Cheng Liu*, Bin Li, and Qing-Xiang Guo, Tetrahedron Lett., 1994, 35, 8429.
2. Study of Mechanism of Reduction of 2-bromo-1-(p-X-phenyl)ethylidenemalononitrile by 1-Benzyl-1,4-dihydronicotinamide and 10-Methyl-9,10-dihydroacridine, You-Cheng Liu*, Bin Li, and Qing-Xiang Guo, Tetrahedron, 1995, 51, 9671.
3. Kinetic studies on the single electron transfer reaction between 2,2,6,6-tetramethyl- piperidine oxoammonium ions  and phenothiazine: the application of Marcus theory. Longmin Wu, Xia Guo, Qingxiang Guo, Zhongli Liu and Youcheng Liu, Science in China (Series B), 1998, 28, 540-546. Science in China (Series B), Engl. Ed. 1999, 42, 138.
4. A Remarkable Kinetic Isotope Effect in One-Electron Transfer from 1-Benzyl-1,4- dihydronicotinamide, Xiao-Qing Zhu*, You-Cheng Liu, Hong-Yi Wang, and Wei Wang, J.Org.Chem., 1999, 64, 8982.
5. Mechanism of reduction of benzylidenemalononitrile by 1-benzyl-1, 4-dihydronicotin-amide. Hongyi. Wang, Youcheng Liu, Xiaoqing Zhu, and Qingxiang. Guo, Chin. J. Chem., 1999, 17, 184-188.
6. Asymmetrical reduction of 2-bromo-1-phenylethylidenemalononitrile with chiral NAD(P)H models, Jing Li, You-Cheng Liu* and Jin-Gen Deng, Tetrahedron-Asymmetry, 1999, 10, 4343.
7. Reduction of o- and p-Bromomethyl benzylidenemalononitrile by 1-Benzyl-1, 4-dihydronicotin- amide. H. Y. Wang, Y. C. Liu, J. Z. Chen, and Q. X. Guo, Chinese Chemical Letters, 1999, 10 (8), 633-636.
8. Which hydrogen atom is first transferred in NAD (P) H model Hantzsch ester (HEH) mediated reactions via one-step and multi-step hydride transfer? Xiaoqing Zhu, Youcheng Liu, Jinpei Cheng, J. Org. Chem., 1999, 64(25), 8980.
9. A remarkable kinetic Isotope effect in one-electron transfer from 1-benxyl-1, 4-dihydronicotinamide. Xiaoqing Zhu, Youcheng Liu, Hongyi Wang and Wei Wang, J. Org. Chem., 1999, 64(35), 8983.
10. Asymmetric reduction of 2-bromo-1-phenylethylidenemalononitrile with chiral NAD (P) H models. Jing Li, You Cheng. Liu, and Jin Gen. Deng, Tetrahedron-Asymmetry, 1999, 10, 4343-4347.
11. 自由基化学,刘有成,刘中立,化学通报199912,17-20。
12. 14N/15N and 12C/13C Equilibrium Isotope Effect on the Electron-Transfer Reaction between N-Methylphenothiazine and Its Radical Cation”. J. Lu, Y. Chen, X. Wen, L. M. Wu, X. Q .Jia, Y. C. Liu and Z. L. Liu, J. Phys. Chem. A, 1999, 103, 6998-7007.
13. N- 烷基吩噻嗪与四氯化碳的光诱导电子转移反应,郭霞,吴隆民,杨 立,刘有成,刘中立,中国科学(B辑)19992,212-219;Science in China(B), 1999, 42, 213-219.
14. Kinetic Studies on the Single Electron Transfer between 2,2,6,6-tetramethylpiperidine Oxoammonium Ions and Phenothiazine: The Application of Marcus Theory, Longmim Wu, Xia Guo, Juan Wang, Zhongli Liu, Youcheng Liu, Science in China (B), 1999, 42, 138-144.
15. Experimental and theoretical studies on the inclusion of b-cyclodextrin with substituted phenothiazines, Q. X. Guo, H. Y. Liu, X. Q. Ruan, X. Q. Zheng, Y. Y. Shi and Y. C. Liu, J. Incl. Phenom., 1999, 35, 487-496.
16. Studies on the driving force for inclusion complexation of a- and b-cyclodextrin with substituted benzenes, H. M. Zhang, S. H. Luo, C. Chen, L. Liu, Q. X. Guo and Y. C. Liu;Chem. Res. Chin. Univ., 1999, 17.
17. Electron transfer between N-substituted phenothiazines and 1-oxopiperidinium ion in the presence of b-cyclodextrin, X. Q. Zheng, X. Q. Ruan, W. Wang, H. M. Zhang, Q. X. Guo and Y. C. Liu, Bull. Chem. Soc. Jpn., 1999, 72, 253-257.
18. BNAH-Mediated Free Radical Addition to Aromatic Imines, Meizhong Jin, Dong Zhang, Li Yang, Youcheng Liu and Zhongli Liu, Tetrahedron Lett., 2000, 41, 7357-7360.
19. 辅酶NADH模型BNAH的光诱导a-羰基环氧化物开环反应, 金美钟, 杨立, 吴隆民, 刘有成, 刘中立, 兰州大学学报(自然科学版), 2000, 36专辑, 134-137。
20. NAD(P)H模型引发的还原环化2,2-双取代-1,2-二氢茚的合成,王宏义,刘有成,郭庆祥,高等学校化学学报200021,79-81。
21. Mechanism of  reduction of 1,1-diphenyl-2,2-dinitroethylene by 1-benzyl-1,4-dihydronicotinamide:transition state with partial diradical and partial covalent bonding character, Youcheng Liu, Hongyi Wang, Qingchuan Yang and Thomas C.W. Mak,
J. Chem. Soc. Perkin Trans., 2000, 2, 649-653.
22. Asymmetric reduction of 2-bromo-1-phenylethylidenemalononitrile with chiral NADH models: substituent effects on enantioselectivity, Jing Li, Youcheng Liu, Jingen Deng, Xingzhu Li, Xing Cui and Zhi Li, Tetrahedron-Asymmetry, 2000, 11, 2677-2682.
23. Cyclizations of 2-(o-bromomethyl)benzylidene-1,3-indandione initiated by 1-benzyl-1,4- dihydronicotinamide and KCN: selectivity of O-alkylation and C-alkylation, Hongyi Wang, Youcheng Liu and Qingxiang Guo, J. Chem. Research(S), 2000, 82-83.
24. An Improved and Efficient Preparation of the Chiral NAD(P)H Model (Ss)-1-Benzyl-3-(p-tolylsulfinyl)- 1,4-dihydro-pyridine, Jing Li, Youcheng Liu, Jingen Deng,  Chin. Chem. Lett., 2000, 11, 209-212.
25. Liquid Chromatographic Resolution of Racemic 2-Phenyl-1,1-cyclopropanedicarbonitrile and its Analogues on Chiral Stationary Phase, Youcheng Liu, Xinzhu Li, Jing Li, Chin. Chem. Lett., 2000, 11, 353-356.
26. 14N/15N Isotope Effect on the Electron Transfer Process between N,N,N’,N’-Tetramethyl-p- phenylenediamine and Wurster’s Blue, J. M. Lu, X. L. Wen, L. M. Wu, Y. C. Liu and Z. L. Liu*, J. Phys. Chem. A, 2001, 105, 6971-6975.  
27. Photochemical Reduction of Aromatic Imines by 2-Phenyl-N, N- dimethylbenzimidazoline, M. Z. Jin, L. Yang, L. M. Wu, Y. C. Liu and Z. L. Liu*, Chin. Chem. Lett., 2001, 12, 307-308.
28. Photochemical Selective Desilylation of  t-Butyldimethylsilyl Ethers, Mei Zhong Jin, Li Yang, Long Ming Wu, You Cheng Liu and Zhong Li Liu*, Chin. Chem. Lett., 2001, 12, 95-98.
29. Application of NAD(P)H Model Hantzsch 1,4-Dihydropyridine as a Mild Reducing Agent in Preparation of Cyclo Compounds,Xiao-Qing Zhu*, Hong-Yi Wang, Jian-Shuang Wang, and You-Cheng Liu, J. Org. Chem., 2001, 66, 344-347.
30. 辅酶NADH模型物还原活化烯烃反应机理研究,刘有成*,李劲,有机化学20012111,898-903。
31. 2,3—二氰基—2,3—二苯基丁二酸二乙酯引发苯乙烯的本体聚合反应,金璟,王海盛,吴隆民*,张自义,刘有成,杨第伦,化学学报2001596,982-985。
32. Photoinduced and Thermal Reactions of α-Cyano-β-bromo-methylcinnamide with 1-Benzyl-1,4-dihydronicotina- mide, DAI, Dan-Mei, LIU, You-Cheng*, LI Jing, Chinese Journal of Chemistry, 2001, 19, 1217-1224.
33. Steroselective Reduction with NADH Model BNAH through Chiral Induction in Cyclodextrins, You-Cheng Liu*, Xin-Zhu Li, Chao Yang, and Qing-Xiang Guo, Bioorganic Chemistry, 2001, 29, 14-18.
34. Novel Photoinduced Coupling Reaction of 9-Fluorenylidenemalononitrile with 10-Methyl-9,10-dihydroacridine, Hong Jiang, You-Cheng Liu*, Jing Li, Guan-Wu Wang, Yun-Dong Wu, Quan-Ming Wang, and Thomas C. W. Mak, Chem.Commun., 2002, 882.
35. Nucleophilic Substitution Reaction of p-Dinitrobenzene by a Carbanion: Evidence for Electron Transfer Mechanism, Liu, You-Cheng, Zhang Kai-Dong, Lu Jian-Ming, Wu Long-Min, Liu Zhong-Li, Chin. J. Chem., 2002, 20, 1453-1456.
36. Photoinducd Electron Transfer in a Supramolecular Species Building of Mono-6-p-nitrobenzoyl-β -cyclodextrin with Naphthalene Derivatives, Y.-H. Wang, H.-M Zhang, L. Liu, Z.-X. Liang, Q.-X. Guo, C.-H. Tung, Y. Inoue, and Y.-C. Liu, J. Org. Chem., 2002, 67, 2429-2434.
37. A Large Conformational Change of a Bridged b-Cyclodextrin Dimer in Aqueous Solution, Xiao Qi ZHENG, Yong Hui WANG, Qing Xiang GUO, Li YANG, You Cheng LIU, Chinese Chemical Letters, 2003, 14(8), 848-851.
38. Novel solvent-free reaction of C60 with active methylene compounds in the presence of Na2CO3 under high-speed vibration  milling, Guan-Wu Wang, Ting-Hu Zhang, Yu-Jin Li, Ping LU, Huan Zhan, You-Cheng Liu, Yasujiro Murata and Koichi Komatsu, Tetrahedron Letters, 2003, 44, 4407-4409.
 

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