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曹小平

【来源:功能有机分子化学国家重点实验室 | 发布日期: | 作者: 】     【选择字号:
曹小平
博士、教授
电话:+86-18919887826
传真:+86-931-8915557
邮箱:caoxp@lzu.edu.cn
 
教育背景、工作经历
2002-至今                兰州大学化学化工学院、功能有机分子化学国家重点实验室,教授
2003, 2008, 2013    德国Bielefeld大学 高级访问学者(短期)
1997-2001               兰州大学化学化工学院、功能有机分子化学国家重点实验室,副教授
1993-1996               香港中文大学,博士
1986-1989               兰州大学,理学硕士
1982-1992               兰州大学,助教、讲师
       1978-1982               兰州大学,理学学士
 
研究兴趣
有机功能分子的设计合成及性质研究,天然产物全合成,有机合成方法学
 
代表成果
1. “Asymmetric Formal Synthesis of (+)-Cycloclavine”. Chen, J.-Q.; Song, L.-L.; Li, F.-X.; Shi, Z.-F.; Cao, X.-P.* Chem. Comm. 2017, 53, 12902–12905.
2. “Total Synthesis of (–)-Chanoclavine I and an Oxygen Substituted Ergoline Derivative” Lu, J.-T.; Shi, Z.-F.; Cao, X.-P.* J. Org. Chem. 2017, 82, 7774–7782.
3. “Efficient Aryl Migration from an Aryl Ether to a Carboxylic Acid Group To Form an Ester by Visible-Light Photoredox Catalysis”. Wang, S.-F.; Cao, X.-P.*; Li, Y.* Angew. Chem., Int. Ed. 2017, 56, 13809–13813. 
4. “Tribenzotriquinacene-Based Crown Ethers: Synthesis and Selective Complexation with Ammonium Salts”. Zhang, Y.-F.; Cao, X.-P.*; Chow, H.-F.*; Kuck, D.* J. Org. Chem. 2017, 82, 179–187.
5. “Triphenylethylene-based Fluorophores: Facile Preparation and Fullcolor Emission in both Solution and Solid States”. Wen, W.; Shi, Z.-F.; Cao, X.-P.*; Xu, N.-S. Dyes and Pigments 2016, 132, 282–290.
6. “o-Quinones Derived from Tribenzotriquinacenes: Functionalization of Inner Bay Positions and Use for Single-Wing Extensions”. Zhang, Y.-F.; Tian, W.-F.; Cao, X.-P.*; Kuck, D.*; Chow, H.-F.* J. Org. Chem. 2016, 81, 2308–2319.
7. “Direct and Short Construction of the ACDE Ring System of Daphenylline”. Wang, W.; Li, G.-P.; Wang, S.-F.; Shi, Z.-F; Cao, X.-P.* Chem. Asian J. 2015, 10, 377–382.
8. “Cyclopropenes for the Synthesis of Cyclopropane-Fused Dihydroquinolines and Benzazepines”. Luo, H.-X.; Niu, Y.-H.; Cao,X.-P.*; Ye, X.-S.* Adv. Synth. Catal. 2015, 357, 2893–2902.
9. “Facile Preparation of a-Cyano-a,w-Diaryloligovinylenes: A New Class of Color-Tunable Solid Emitters”. An, P.; Xu, N.-S.; Zhang, H.-L.; Cao,X.-P.*, Shi, Z.-F.*, Wen, W. Chem. Asian J. 2015, 10, 1959–1966.
10. “Versatile Syntheses of Hemi-Cryptophanes and a Metallo-Cryptophane from a Hexa-Functionalized C3v-Symmetrical Tribenzotriquinacene (TBTQ) Derivative”. Wei, J.; Li, Z.-M.; Jin, X.-J.; Yao, X.-J.; Cao, X.-P.*; Chow, H.-F.*; Kuck, D.* Chem. Asian J. 2015, 10, 1150–1158.
11. “Facile Assembly of Chiral Metallosquares by Using Enantionpure Tribenzotriquinacene Corner Motifs”. Xu, W.-R.; Xia, G.-J.: Chow, H.-F.*; Cao, X.-P.*; Kuck, D.* Chem. Eur. J. 2015, 21, 12011–12017.
12. “Formal Synthesis of (±)-Cycloclavine”. Wang, W.; Lu, J.-T.; Zhang, H.-L.; Shi, Z.-F.; Wen, J.; Cao, X.-P.* J. Org. Chem. 2014, 79, 122–127.
13. “A Phosphine-catalyzed Regioselective [3+2] Cycloaddition of Ethyl 5,5-Diarylpenta-2,3,4-trienoate with Aromatic Aldehydes and a,β-Unsaturated Carbonyl Compounds”. Wang, L.-F.; Cao, X.-P.*; Shi, Z.-F.*; An, P.; Chow, H.-F. Adv. Synth. Catal. 2014, 356, 3383–3390.
14. “Construction of Fused- and Spiro-oxa-[n.2.1] Skeletons by a Tandem Epoxide Rearrangement/intramolecular [3+2] Cycloaddition of Cyclopropanes with Carbonyls”. Wang, L.-F.; Shi, Z.-F*; Cao, X.-P.*, Li, B.-S.; An, P. Chem. Commun. 2014, 50, 8061–8064.
15. “FeCo–Nx Embedded Graphene as High Performance Catalysts for Oxygen Reduction Reaction”. Fu, X.; Liu, Y.; Cao, X.-P.*; Jin, J.; Liu, Q.; Zhang, J.* Appl. Catal. B: Environ. 2013, 130131, 143–151.
16. “Direct Syntheses of Spiro- and Fused-Hydrofurans by a Tunable Tandem Semipinacol Rearrangement/Oxa-Michael Addition Protocol”. Li, B.-S.; Liu, W.-X.; Zhang, Q.-W.;  Wang, S.-H.; Zhang, F.-M.; Zhang, S.-Y.; Tu, Y.-Q.*; Cao, X.-P.* Chem. Eur. J. 2013, 19, 5246–5249.
17. “C3-Symmetrical Tribenzotriquinacene Derivatives: Optical Resolution through Cryptophane Synthesis and Supramolecular Self-Assembly into Nanotubes”. Wang, T.; Zhang, Y.-F.; Hou, Q.-Q.; Xu, W.-R.; Cao, X.-P.*; Chow, H.-F.*; Kuck, D.*J. Org. Chem. 2013, 78, 1062–1069.
18. “Copper(I)-catalyzed Intramolecular [2+2] Cycloaddition of 1,6-Enyen-derived Ketenimine: an Efficient Construction of Strained and Bridged 7-Substituted-3-heterobicyclo[3.1.1]heptan-6-one”. Li, B.-S.; Yang, B.-M.; Wang, S.-H.;  Zhang, Y.-Q.; Cao, X.-P.*; Tu, Y.-Q.* Chem. Sci. 2012, 3, 1975–1979.
19. “Synthesis of Polyisoprene Terpenoid Dendrons and their Applications in Oligo(phenylene ethynylene)s as ‘Shells’ ”. Chai, W.-Y.; Shi, Z.-F.; An, P.; Wang, W.; Wang, L.-F.; Cao, X.-P.* Chem. Asian J. 2012, 7, 143–155.
20. “Single-wing Extended Tribenzotriquinacenes via Bowl-shaped Dehydrobenzene and Isobenzofuran Tribenzotriquinacene Derivatives”. Niu, W.-X.; Yang, E.-Q.; Shi, Z.-F.; Cao, X.-P.*; Kuck, D.* J. Org. Chem. 2012, 77, 1422–1434.
 

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