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曹小平

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曹小平

博士、教授

电话:+86-18919887826

传真:+86-931-8915557

邮箱:caoxp@lzu.edu.cn

·教育背景、工作经历

2002-至今            兰州大学化学化工学院、功能有机分子化学国家重点实验室,教授

2003, 2008, 2013 德国Bielefeld大学 高级访问学者(短期)

1997-2001           兰州大学化学化工学院、功能有机分子化学国家重点实验室,副教授

1993-1996           香港中文大学化学系 (导师: 周克勋 教授),哲学博士

1986-1989           兰州大学化学系,理学硕士

1982-1992           兰州大学化学系,助教、讲师

1978-1982           兰州大学,理学学士

·研究兴趣

有机功能分子的设计合成及性质研究,天然产物全合成,有机合成方法学

·代表成果

1. Enantioselective Formal Synthesis of (+)-Cycloclavine and Total Synthesis of (+)-5-epi-Cycloclavine, Wei Wang, Yang Mi, Xiao-Ping Cao*, and Zi-Fa Shi*, Org. Lett. 2019, 21, 6603−6607.

2. Access to Benzylic Quaternary Carbons from Aromatic Ketones, You Li, Jingpeng Han, Han Luo, Qiaoyu An, Xiao-Ping Cao*, and Baosheng Li*, Org. Lett. 2019, 21, 6050−6053.

3. Access to Sulfides through Free Radical Reaction of Vinyl Halides with Thiols, Zi-Fa Shi*, Li-Ning Xu, Jie Chen, Hui-Xing Luo, Juntao Zhang, and Xiao-Ping Cao*, Asian J. Org. Chem. 2019, 8, 161–170.

4. Biconcave and Convex-Concave Tribenzotriquinacene Dimers, Zhi-Min Li, Ya-Wei Li, Xiao-Ping Cao*, Hak-Fun Chow*, and Dietmar Kuck*, J. Org. Chem. 2018, 83, 3433–3440 (Highlighted by SYNFACTS 2018, 14, 0698).

5. Construction of the Tetracyclic Core of (±)-Cycloclavine and 4-Amino Uhle’s Ketone, Jin-Quan Chen, Yang Mi, Zi-Fa Shi, and Xiao-Ping Cao*, Org. Biomol. Chem. 2018, 16, 3801–3808.

6. An Efficient Ag+-Selective Fluorescent Chemosensor Derived from Tribenzotriquinacene, Zhi-Min Li, Da Hu, Jun Wei, Qiuli Qi, Xiao-Ping Cao*, Hak-Fun, Chow*, and Dietmar Kuck*, Synthesis 2018, 50, 1457–1461.

7. Visible-Light Photoredox-Catalyzed Iminyl Radical Formation by N−H Cleavage with Hydrogen Release and Its Application in Synthesis of Isoquinolines, Wan-Fa Tian, Dang-Po Wang, Shao-Feng Wang, Ke-Han He, Xiao-Ping Cao, and Yang Li*, Org. Lett. 2018, 20, 1421−1425.

8. “Asymmetric Formal Synthesis of (+)-Cycloclavine”. Chen, J.-Q.; Song, L.-L.; Li, F.-X.; Shi, Z.-F.; Cao, X.-P.* Chem. Commun. 2017, 53, 12902–12905.

9. “Total Synthesis of (−)-Chanoclavine I and an Oxygen Substituted Ergoline Derivative” Lu, J.-T.; Shi, Z.-F.; Cao, X.-P.* J. Org. Chem. 2017, 82, 7774–7782.

10. “Efficient Aryl Migration from an Aryl Ether to a Carboxylic Acid Group To Form an Ester by Visible-Light Photoredox Catalysis”. Wang, S.-F.; Cao, X.-P.*; Li, Y.* Angew. Chem., Int. Ed. 2017, 56, 13809–13813. 

11. “Tribenzotriquinacene-Based Crown Ethers: Synthesis and Selective Complexation with Ammonium Salts”. Zhang, Y.-F.; Cao, X.-P.*; Chow, H.-F.*; Kuck, D.* J. Org. Chem. 2017, 82, 179–187. 

12. “Triphenylethylene-based Fluorophores: Facile Preparation and Fullcolor Emission in both Solution and Solid States”. Wen, W.; Shi, Z.-F.; Cao, X.-P.*; Xu, N.-S. Dyes and Pigments, 2016, 132, 282–290.

13. “O-Quinones Derived from Tribenzotriquinacenes: Functionalization of Inner Bay Positions and Use for Single-Wing Extensions”. Zhang, Y.-F.; Tian, W.-F.; Cao, X.-P.*; Kuck, D.*; Chow, H.-F.* J. Org. Chem. 2016, 81, 2308–2319.

14. “Direct and Short Construction of the ACDE Ring System of Daphenylline”. Wang, W.; Li, G.-P.; Wang, S.-F.; Shi, Z.-F; Cao, X.-P.* Chem. Asian J. 2015, 10, 377–382.

15. “Cyclopropenes for the Synthesis of Cyclopropane-Fused Dihydroquinolines and Benzazepines”. Luo, H.-X.; Niu, Y.-H.; Cao,X.-P.*; Ye, X.-S.* Adv. Synth. Catal. 2015, 357, 2893–2902.

16. “Facile Preparation of-Cyano-,-Diaryloligovinylenes: A New Class of Color-Tunable Solid Emitters”. An, P.; Xu, N.-S.; Zhang, H.-L.; Cao,X.-P.*, Shi, Z.-F.*, Wen, W. Chem. Asian J. 2015, 10, 1959–1966.

17. “Versatile Syntheses of Hemi-Cryptophanes and a Metallo-Cryptophane from a Hexa-Functionalized C3v-Symmetrical Tribenzotriquinacene (TBTQ) Derivative”. Wei, J.; Li, Z.-M.; Jin, X.-J.; Yao, X.-J.; Cao, X.-P.*; Chow, H.-F.*; Kuck, D.* Chem. Asian J. 2015, 10, 1150–1158.

18. “Facile Assembly of Chiral Metallosquares by Using Enantionpure Tribenzotriquinacene Corner Motifs”. Xu, W.-R.; Xia, G.-J.: Chow, H.-F.*; Cao, X.-P.*; Kuck, D.* Chem. Eur. J. 2015, 21, 12011–12017. 

19. “Formal Synthesis of (±)-Cycloclavine”. Wang, W.; Lu, J.-T.; Zhang, H.-L.; Shi, Z.-F.; Wen, J.; Cao, X.-P.* J. Org. Chem. 2014, 79, 122–127. 

20. “A Phosphine-catalyzed Regioselective [3+2] Cycloaddition of Ethyl 5, 5-Diarylpenta-2, 3, 4-trienoate with Aromatic Aldehydes and β-Unsaturated Carbonyl Compounds”. Wang, L.-F.; Cao, X.-P.*; Shi, Z.-F.*; An, P.; Chow, H.-F. Adv. Synth. Catal. 2014, 356, 3383–3390. 

21. “Construction of Fused- and Spiro-oxa-[n.2.1] Skeletons by a Tandem Epoxide Rearrangement/intramolecular [3+2] Cycloaddition of Cyclopropanes with Carbonyls”. Wang, L.-F.; Shi, Z.-F*; Cao, X.-P.*, Li, B.-S.; An, P. Chem. Commun. 2014, 50, 8061–8064.

22. “FeCo–Nx Embedded Graphene as High Performance Catalysts for Oxygen Reduction Reaction”. Fu, X.; Liu, Y.; Cao, X.-P.*; Jin, J.; Liu, Q.; Zhang, J.* Appl. Catal. B: Environ. 2013, 130–131, 143–151.

23. “Direct Syntheses of Spiro- and Fused-Hydrofurans by a Tunable Tandem Semipinacol Rearrangement/Oxa-Michael Addition Protocol”. Li, B.-S.; Liu, W.-X.; Zhang, Q.-W.;  Wang, S.-H.; Zhang, F.-M.; Zhang, S.-Y.; Tu, Y.-Q.*; Cao, X.-P.* Chem. Eur. J. 2013, 19, 5246–5249.

24. “C3-Symmetrical Tribenzotriquinacene Derivatives: Optical Resolution through Cryptophane Synthesis and Supramolecular Self-Assembly into Nanotubes”. Wang, T.; Zhang, Y.-F.; Hou, Q.-Q.; Xu, W.-R.; Cao, X.-P.*; Chow, H.-F.*; Kuck, D.* J. Org. Chem. 2013, 78, 1062–1069.

25. “Copper(I)-catalyzed Intramolecular [2+2] Cycloaddition of 1,6-Enyen-derived Ketenimine: an Efficient Construction of Strained and Bridged 7-Substituted-3-heterobicyclo[3.1.1] heptan-6-one”. Li, B.-S.; Yang, B.-M.; Wang, S.-H.;  Zhang, Y.-Q.; Cao, X.-P.*; Tu, Y.-Q.* Chem. Sci. 2012, 3, 1975–1979.

26. “Synthesis of Polyisoprene Terpenoid Dendrons and their Applications in Oligo(phenylene ethynylene)s as‘Shells’”. Chai, W.-Y.; Shi, Z.-F.; An, P.; Wang, W.; Wang, L.-F.; Cao, X.-P.* Chem. Asian J. 2012, 7, 143–155.

27. “Single-wing Extended Tribenzotriquinacenes via Bowl-shaped Dehydrobenzene and Isobenzofuran Tribenzotriquinacene Derivatives”. Niu, W.-X.; Yang, E.-Q.; Shi, Z.-F.; Cao, X.-P.*; Kuck, D.* J. Org. Chem. 2012, 77, 1422–1434.

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