兰州大学功能有机分子化学国家重点实验室页头logo

搜索
研究队伍
首页 > 研究队伍 > 教授

舒兴中

未标题-1.jpg

舒兴中

博士、教授、博士生导师

电话:+86-931-8911976

邮箱:shuxingzh@lzu.edu.cn

课题组主页:http://shulab.lzu.edu.cn

•教育背景、工作经历

2015-至今            兰州大学化学化工学院、功能有机分子化学国家重点实验室,教授、博导

2012-2015           加州大学伯克利分校/劳伦斯伯克利国家实验室 (导师: F. Dean Toste教授),博士后

2010-2012           威斯康辛大学麦迪逊分校 (导师: Weiping Tang教授),博士后

2005-2010           兰州大学 (导师: 梁永民 教授),理学博士

2001-2005           绍兴文理学院,学士

•荣誉奖励

      2022                    国华青年英才奖

      2020                    Thieme Chemistry Journals Award

      2009                    中国青少年科技创新奖

      2008                    宝钢教育奖学金

•研究兴趣

研究兴趣为有机合成方法学。目前主要的研究方向包括:(1)非活性C-O键还原偶联化学;(2)氯硅(锗)烷还原偶联化学;(3)不对称还原偶联化学。

•代表成果 

1. Enantioselective Reductive N‑Cyclization Alkylation Reaction of Alkene-Tethered Oxime Esters and Alkyl Iodides by Nickel Catalysis. Xuegong Jia, Qiwei Yao, and Xingzhong Shu*, J. Am. Chem. Soc. 2022, 144, 13461.

2. Nickel-Catalyzed Reductive C(sp2)-Si Coupling of Chlorohydrosilanes via Si-Cl Cleavage. Zhenzhen Zhao, Xiaobo Pang, Xiaoxue Wei, Xueyuan Liu and Xingzhong Shu*, Angew. Chem. Int. Ed. 2022, 61, e202200215.

3. Nickel-Catalyzed Cross-Electrophile 1,2-Silyl-Arylation of 1,3-Dienes with Chlorosilanes and Aryl Bromides. Qiuquan Pan, Liangliang Qi, Xiaobo Pang, and Xing-Zhong Shu*, Angew. Chem. Int. Ed. 2022, DOI:10.1002/anie.202215703, e202215703.

4. Reductive Cross-Coupling of Unreactive Electrophiles. Xiaobo Pang, Pei-Feng Su, and Xing-Zhong Shu*, Acc. Chem. Res. 2022, 55, 2491.

5. Ti-Catalyzed Reductive Dehydroxylative Vinylation of Tertiary Alcohols. Hao Xie, Sheng Wang, Yuquan Wang, Peng Guo and Xing-Zhong Shu*, ACS Catal. 2022, 12, 1018.

6. Reductive Alkylation of Alkenyl Acetates with Alkyl Bromides by Nickel Catalysis. Rong-De He, Yunfei Bai, Guan-Yu Han, Zhen-Zhen Zhao, Xiaobo Pang, Xiaobo Pan, Xue-Yuan Liu, Xing-Zhong Shu*. Angew. Chem. Int. Ed2021, 61, DOI:10.1002/anie.202114556

7. Nickel-Catalyzed Reductive C−Ge Coupling of Aryl/Alkenyl Electrophiles with Chlorogermanes. Pei-Feng Su, Ke Wang, Xuejing Peng, Xiaobo Pang, Peng Guo, and Xing-Zhong Shu*. Angew. Chem. Int. Ed202160, 26571-26576.

8. Cobalt-Catalyzed Enantiospecific Dynamic Kinetic Cross-Electrophile Vinylation of Allylic Alcohols with Vinyl Triflates. Wei-Yuan Ma, Guan-Yu Han, Shaolin Kang, Xiaobo Pang, Xue-Yuan Liu, Xing-Zhong Shu. J. Am. Chem. Soc. 2021143, 15930-15935.

9. Enantioselective Reductive Divinylation of Unactivated Alkenes by Nickel-Catalyzed Cyclization Coupling Reaction. Jin-Bao Qiao, Ya-Qian Zhang, Qi-Wei Yao, Zhen-Zhen Zhao, Xuejing Peng, and Xing-Zhong Shu. J. Am. Chem. Soc. 2021143, 12961-12967.

10. Regiocontrolled Reductive Vinylation of Aliphatic 1,3-Dienes with Vinyl Triflates by Nickel Catalysis. Xiaobo Pang, Zhen-Zhen Zhao, Xiao-Xue Wei, Liangliang Qi, Guang-Li Xu, Jicheng Duan, Xue-Yuan Liu, and Xing-Zhong Shu. J. Am. Chem. Soc. 2021143, 4536-4542.

11. Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis. Peng Guo, Ke Wang, Wen-Jie Jin, Hao Xie, Liangliang Qi, Xue-Yuan Liu, and Xing-Zhong Shu. J. Am. Chem. Soc. 2021, 143, 513-523.

12. Nickel-Catalyzed Cross-Electrophile C(sp3)-Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes. Jicheng Duan, Yuquan Wang, Liangliang Qi, Peng Guo, Xiaobo Pang, Xing-Zhong Shu*, Org. Lett. 202123, 7855-7859.

13. Nickel-Catalyzed Cross-Electrophile C(sp3)–Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes. CCS Chem.20213, 1147-1154.

14. Titanium: a Unique Metal for Radical Dehydroxylative Functionalization of Alcohols. Xiaobo Pang, Xing-Zhong Shu*, Synlett 202132, 1269-1274.

15. Synthesis of Dibenzyls Synthesis by Nickel-Catalyzed Homocoupling of Benzyl Alcohols. Feng-Feng Pan, Peng Guo, Xiaochuang huang, Xing-Zhong Shu*, Synthesis-Stuttgart 202153, 3094-3100.

16. Cross-Electrophile Csp2-Si Coupling of Vinyl Chlorosilanes. Jicheng Duan, Ke Wang, Guangli Xu, Shaolin Kang, Liangliang Qi, Xueyuan Liu, and Xingzhong Shu*. Angew. Chem. Int. Ed202059, 23083-23088.

17Radical Dehydroxylative Alkylation of Tertiary Alcohols by Ti Catalysis. Hao Xie, Jiandong Guo, Yuquan Wang, Ke Wang, Peng Guo, Peifeng Su, Xiaotai Wang*, and Xingzhong Shu*. J. Am. Chem. Soc. 2020142, 16787-16794.

18. Allylboronates from Vinyl Triflates and α-Chloroboronates by Reductive Nickel Catalysis. Jinbao Qiao, Zhenzhen Zhao, Yaqian Zhang, Kai Yin, Zhixiong Tian, and Xingzhong Shu*. Org. Lett. 202022, 5085-5089.

19. Reductive Coupling between C-N and C-O Electrophiles. Rongde He, Chunling Li, Qiuquan Pan, Peng Guo, Xueyuan Liu, and Xingzhong Shu*. J. Am. Chem. Soc. 2019141, 12481-12486.

20. Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes. Zhixiong Tian, Jinbao Qiao, Guangli Xu, Xiaobo Pang, Liangliang Qi, Weiyuan Ma, Zhenzhen Zhao, Jicheng Duan, Yunfei Du, Peifeng Su, Xueyuan Liu, and Xingzhong Shu*. J. Am. Chem. Soc. 2019141, 7637-7643.

21. Ni-catalyzed cross-electrophile coupling between vinyl/aryl and alkyl sulfonates: synthesis of cycloalkenes and modification of peptides. Jicheng Duan, Yunfei Du, Xiaobo Pang, and Xingzhong Shu*. Chem. Sci. 201910, 8706-8712.

22. Enones from Acid Fluorides and Vinyl Triflates by Reductive Nickel Catalysis. Fengfeng Pan, Peng Guo, Chunling Li, Peifeng Su, and Xingzhong Shu*. Org. Lett. 201921, 3701-3705. 

23. Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols. Xuegong Jia, Peng Guo, Jicheng Duan, and Xingzhong Shu*. Chem. Sci. 20189, 640-645.

24. Reductive coupling of benzyl oxalates with highly functionalized alkyl bromides by nickel catalysis. Xiaobiao Yan, Chunling Li, Wenjie Jin, Peng Guo, and Xingzhong Shu*. Chem. Sci. 20189, 4529-4534.

25. Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and Enantioselective Lactonization Reactions. Xingzhong Shu, Son C. Nguyen, Ying He, Fadekemi Oba, Qiao Zhang, Christian Canlas, Gabor A. Somorjai*, A. Paul Alivisatos*, and F. Dean Toste*. J. Am. Chem. Soc. 2015137, 7083.

26. Dual Visible Light Photoredox and Gold-catalyzed Arylative Ring Expansion. Xingzhong Shu, Miao Zhang, Ying He, Heinz, Frei*, and F. Dean Toste*. J. Am. Chem. Soc. 2014136, 5844.

27. Transfer of Chirality in Rhodium-Catalyzed Intramolecular (5+2) Cycloaddition of 3-Acyloxy-1, 4-enyne (ACE) and Alkyne: Enantioselective Synthesis of Bicyclo[5.3.0]decatrienes. Xingzhong Shu, Casi M. Schienebeck, Wangze Song, Ilia A. Guzei, and Weiping Tang*. Angew. Chem. Int. Ed. 201352, 13601.

28. Rhodium-Catalyzed Intra- and Intermolecular 5+2 Cycloaddition of 3-Acyloxy-1, 4-enyne and Alkyne with Concomitant 1, 2-Acyloxy Migration, Xingzhong Shu, Xiaoxun Li, Dongxu Shu, Suyu Huang, Casi Mae Schienebeck, Xin Zhou, Patrick J. Robichaux, and Weiping Tang. J. Am. Chem. Soc. 2012134, 5211. 

联系我们

Copyrights © All Rights Reserved 版权所有 兰州大学功能有机分子化学国家重点实验室 陇ICP备10000336号

事业单位