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杨尚东

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杨尚东

博士、教授

电话:+86-931-8912859

传真:+86-931-8912859

邮箱: yangshd@lzu.edu.cn

•教育背景、工作经历

2009-至今            兰州大学化学化工学院、功能有机分子化学国家重点实验室,教授

2007-2009           芝加哥大学化学系 (导师: 何川),博士后

2006-2007           北京大学 (导师: 施章杰),博士后

2003-2006           兰州大学 (导师: 梁永民),理学博士

1997-2003           甘肃电力科学研究院工作,工程师

1993-1997           兰州大学,理学学士

•荣誉奖励

2015                    Thieme Chemistry Journal Award奖

2013                    中国百篇最具影响国际学术论文奖

2013                    国家自然科学二等奖(排名第四)

•研究兴趣

有机磷化学,不对称合成

•代表成果 

1.“Pd-Catalyzed Heck-Type Reaction: Synthesizing Highly Diastereoselective and Multiple Aryl-Substituted P‑Ligands,” Chong Li, Xiao-Yue Qiang, Zhi-Chao Qi, Bin Cao, Jing-Yu Li, Shang-Dong Yang*, Org. Lett., 2019, 21, 7138−7142.

2.“Visible photocatalysis of novel oxime phosphonates: synthesis of β-aminophosphonates,” Yong-Hong Li, Chun-Hai Wang, Su-Qian Gao, Feng-Ming Qi and Shang-Dong Yang*, Chem. Comm., 2019, 55, 11888−11891.

3.“Palladium−NHC-Catalyzed Allylic Alkylation of Pronucleophiles with Alkynes,” Wei Ren, Qian-Ming Zuo, Yan-Ning Niu and Shang-Dong Yang*, Org. Lett., 2019, 21, 7956−7960.

4.“Applications of transition metal catalyzed P-radical for synthesis of organophosphorus compounds,” Wei Ren, Qiang Yang and Shangdong Yang*, Pure Appl. Chem., 2019, 91, 87–94.

5.“NHCs-Catalyzed the Synthesis of Benzazole-Phoshpine Ligands under Air Condition.” Wei Ren, Qian-Ming Zuo and Shang-Dong Yang* Synlett, 2019, 30, 1719−1724. 

6.“Visible-light-induced tandem phosphorylation cyclization of vinyl azides under mild conditions,” Yonghong Li, Yuanyuan Zhu and Shang-Dong Yang*, Org. Chem. Front., 2018, 5, 822−826.

7.“Rh(III)-Catalyzed Phosphine Oxide Migration Reactions: Selective Synthesis of 3-Phosphinoylindoles,” Chun-Hai Wang, and Shang-Dong Yang*, Chem. Asian J. 2018, 13, 2401−2404.

8.“Autoxidation Photoredox Catalysis for the Synthesis of 2‑Phosphinoylindoles,” Chun-Hai Wang, Yong-Hong Li and Shang-Dong Yang*, Org. Lett., 2018, 20, 2382– 2385.

9.“Visible-Light-Catalyzed Phosphonation-Annulation: An Efficient Strategyto Synthesize β-Phosphonopyrrolidines and β-Phosphonolactones,” Chong Li, Zhi-Chao Qi, Qiang Yang, Xiao-Yue Qiang and Shangdong Yang*, Chin. J. Chem. 2018, 36, 1052–1058.

10.“Direct Allylic C(sp3)‑H Alkylation with 2‑Naphthols via Cooperative Palladium and Copper Catalysis: Construction of Cyclohexadienones with Quaternary Carbon Centers.” Ming Jin, Wei Ren, Dang-Wei Qian and Shang-Dong Yang* Org. Lett. 2018, 20, 7015−7019.

11.“Photocatalyzed Intermolecular Aminodifluoromethylphosphonation of Alkenes: Facile Synthesis of a,a-Difluoro-g-aminophosphonates,” Qiang Yang, Chong Li, Zhi-Chao Qi, Xiao-Yue Qiang and Shang-dong Yang*, Chem. Eur. J. 2018, 24, 14363–14367.

12.“New Approaches for Biaryl-Based Phosphine Ligand Synthesis via P=O Directed C−H Functionalizations". Ma, Y.-N.; Li, S.-X. and Yang, S.-D.* Acc. Chem. Res. 2017, 50, 1480−1492.

13.“Highly Efficient and Divergent Construction of Chiral γ‑Phosphono-α-Amino Acids via Palladium-Catalyzed Alkylation of Unactivated C(sp3)−H Bonds". Yang, Q.; Yang, S.-D.* ACS Catal. 2017, 7, 5220−5224.

14. “Direct Allylic C−H Bond Activation To Synthesize [Pd(η3‑cin)(IPr)Cl] Complex: Application in the Allylation of Oxindoles". Hu, R.-B.; Wang, C.-H.; Ren, W.; Liu, Z.; Yang, S.-D.* ACS Catal. 2017, 7, 7400−7404.

15. “Diastereoselective Radical Oxidative C−H Aminations toward Chiral Atropoisomeric (P, N) Ligand Precursors". Ma, Y.-N.; Cheng, M.-X.; Yang, S.-D.* Org. Lett. 2017, 19, 600−603.

16.“Palladium-Catalyzed Migratory Insertion of Isocyanides for Synthesis of C‑Phosphonoketenimines". Yang, Q.; Li, C.; Cheng, M.-X.; Yang, S.-D.* ACS Catal. 2016, 6, 4715−4719.

17. “Palladium-Catalyzed Migratory Insertion of Isocyanides for Synthesis of C‑Phosphonoketenimines". Yang, Q.; Li, C.; Cheng, M.-X.; Yang, S.-D.* ACS Catal. 2016, 6, 4715−4719.

18.“Enantioselective synthesis of arylglycine derivatives by direct C–H oxidative cross-coupling". Wei, X.-H.; Wang, G.-W.; Yang, S.-D.* Chem. Commun., 2015, 51, 832–835.

19.“A unique Copper-catalyzed Cross-coupling Reaction by Hydrogen (H2) Removal for the Stereoselective Synthesis of 3-phosphoindoles". Zhou, A.-X.; Mao, L.-L.; Wang, G.-W.; Yang, S.-D.* Chemm. Commun. 2014, 50, 8529–8532.

20.“Regio- and Stereoselective Allylic C−H Arylation with Electron-Deficient Arenes by 1, 1′-Bi-2-naphthol−Palladium Cooperation". Wang, G.-W.; Zhou, A.-X.; Li, S.-X.; Yang, S.-D.* Org. Lett. 2014, 16, 3118–3121.

21.“Direct Annulations toward Phosphorylated Oxindoles by Silver-Catalyzed Carbon-phosphorus Functionalization of Alkenes". Li, Y.-M.; Sun, M.; Wang, H.-L.; Tian, Q.-P.; Yang, S.-D.* Angew. Chem. Int. Ed., 2013, 52, 3972–3976.

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